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Enhanced 4-chlorophenol biodegradation by integrating FeO nanoparticles into an anaerobic reactor: Long-term

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 8, doi: 10.1007/s11783-022-1519-6

Abstract:

• 4-chlorophenol biodegradation could be enhanced in Fe2sub>O3sub> coupled anaerobic system.

Keywords： Dechlorination Fe2sub>O3sub> nanoparticles Electron transfer Microbial community

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Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4, Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2sub>O3sub> CePO4sub> N2sub>O decomposition

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The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2sub>O3sub> with a small amount, wasintroduced into Pb/SiO2sub> catalyst in this study.It has been proved that Al2sub>O3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O3sub> addition was also proposed.

Keywords： Pb/SiO2sub> Al2sub>O3sub> propane dehydrogenation propene stability

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Size and shape effects of MnFeO nanoparticles as catalysts for reductive degradation of dye pollutants

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 5, Pages 108-171 doi: 10.1007/s11783-021-1396-4

Abstract: The magnetic nanoparticles that are easy to recycle have tremendous potential as a suitable catalystHerein, we successfully synthesized three kinds of MnFe2sub>O4sub> NPs with distinctiveIt was found that the catalytic activities were dependent on the size and shape of the MnFe2subFurthermore, the MnFe2sub>O4sub> NPs could be readily recovered by a magnet and reusedThe size and shape effects of MnFe2sub>O4sub> nanoparticles demonstrated in this work not

Keywords： Dye degradation MnFe2sub>O4sub> nanoparticles Size and shape-control

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Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2sub>O3sub> Systemwith Al2sub>O3sub> and Cr2sub>O3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6, Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr2O3 system with AI2O3and Cr2O3 diluents were conducted, and the effects of reactionstarting temperature TO, diluents AI2O3 and Cr2O3 on the adiabatic combustion temperature

Keywords： cermet combustion synthesis Al - Cr2sub>O3sub> system thermodynamics reaction model

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Sulfur-deficient CoNi2sub>S4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11, Pages 1707-1717 doi: 10.1007/s11705-023-2308-x

Abstract: >2sub>S4sub> nanoparticles are prepared as bifunctional electrocatalyst.>2sub>S4sub>.>2sub>S4sub> from 1.68 to 0.52 eV.Moreover, the uniform distribution of CoNi2sub>S4sub> nanoparticles on carbon nanofibersevolution reaction and 380 mV@100 mA·cm^–2 for hydrogen evolution reaction.

Keywords： nanoparticle sulfur vacancy porous carbon nanofiber transition metal sulfides electrolysis

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CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2, Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords： Mn promotion nickel catalysts CO2sub> methanation co-methanation of CO and CO2sub>

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Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1, Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords： CO2sub> capture MgO sorbents Al2sub>O3sub> CeO2sub> flue gas

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In-MOF-derived In2sub>S3sub>/Bi2sub>S3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5, Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In2sub>S3sub>/Bi2sub>S3sub> heterojunctionis constructed by in-situ integrating Bi2sub>S3sub> with the In2sub>S2sub>S3sub>/Bi2sub>S3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In2sub>S3sub> (0.32 mmol/(g∙h) and Bi2sub>S3sub> (0.41 mmol/(g∙h)), respectively.

Keywords： photocatalytic hydrogen production wide-spectrum response metal sulfides MOFs derivative heterogeneous interfacial contact

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Fe3sub>O4sub> encapsulated mesoporous silica nanospheres with tunable size and large void

Tingting LIU, Lihong LIU, Jian LIU, Shaomin LIU, Shi Zhang QIAO

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 1, Pages 114-122 doi: 10.1007/s11705-014-1413-2

Abstract: Magnetic Fe O and mesoporous silica core-shell nanospheres with tunable size from 110–800 nm were synthesized via a one step self-assembly method. The morphological, structural, textural, and magnetic properties were well-characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, N adsorption-desorption and magnetometer. These nanocomposites, which possess high surface area, large pore volume and well-defined pore size, exhibit two dimensional hexagonal ( 6mm) mesostructures. Interestingly, magnetic core and mesoporous silica shell nanocomposites with large void pore (20 nm) on the shell were generated by increasing the ratio of ethanol/water. Additionally, the obtained nanocomposites combined magnetization response and large void pore, implying the possibility of applications in drug/gene targeting delivery. The cell internalization capacity of NH -functionalized nanocomposites in the case of cancer cells (HeLa cells) was exemplified to demonstrate their nano-medicine application.

Keywords： mesoporous silicas magnetic nanoparticles core-shell nanoparticles cell uptake

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Effects of iron oxide nanoparticles on phenotype and metabolite changes in hemp clones ( L.)

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1569-9

Abstract:

● Fe3sub>O4sub> NPs increased the biomass and chlorophyll

Keywords： Fe3sub>O4sub> nanoparticle Hemp Growth enhancement THC Metabolite

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Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 1, Pages 1-14 doi: 10.1007/s11705-022-2176-9

Abstract: Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO2sub>–TiO2sub>2sub>–TiO2sub> coated steel.The enhanced ATA/SiO2sub>–TiO2sub> nanoparticles inhibited the entry of electrolytes intoWhen the concentration of ATA/SiO2sub>−TiO2sub> nanoparticles was 2 wt %, dynamic mechanicalbarrier and mechanical properties due to the addition of ATA/SiO2sub>–TiO2sub> nanoparticles

Keywords： SiO2sub>/TiO2sub> nanoparticle nanocomposite coatings dynamic mechanical analysis electrochemical

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Feasibility study of plasma sprayed Al2sub>O3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Frontiers of Mechanical Engineering 2012, Volume 7, Issue 4, Pages 371-375 doi: 10.1007/s11465-012-0339-y

Abstract: Within this study the feasibility of plasma sprayed Al2sub>O3sub> coatings as diffusionAl2sub>O3sub> coatings were prepared by air plasma spraying (APS).The results showed that Al2sub>O3sub> could be well deposited onto CFC substrates.temperature of 1270°C, crack network formed within the coating, showing that the plasma sprayed Al2sub>O3sub> coatings are limited regarding to their application temperatures as diffusion

Keywords： diffusion barrier coatings CFC plasma spraying microstructure Al2sub>O3sub>

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Spray Preparation, Microstructure and Properties of Al2sub>O3sub>-Mxsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Strategic Study of CAE 2002, Volume 4, Issue 9, Pages 75-80

Abstract: carbon steel substrate, base coating of nickel-coated aluminium and intermediate coating of 50% Al2sub>O3sub> + 50% Ni were prepared by means of oxyacetylene spray, and final coating of Al2sub>O3sub> ～ Mxsub>Oysub> was prepared by means of plasma spray.of 60% (mass) sulphuric acid with 60 % concentration, and 40% (mass) phosphoric ore powder, the Al2sub>O3sub> ～ Mxsub>Oysub> coating resistance to corrosion and wear, is 7.46

Keywords： Al2sub>O3sub>-Mxsub>Oysub> coating plasma resistance to corrosion resistance

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of promoted rice (Oryza sativa L.) growth by TiO2sub> nanoparticles

Yingdan Zhang, Na Liu, Wei Wang, Jianteng Sun, Lizhong Zhu

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 6, doi: 10.1007/s11783-020-1282-5

Abstract: Abstract • The rice growth was promoted by nano-TiO2 of 0.1–100 mg/L. • Nano-TiO2 enhanced the energystorage in photosynthesis. • Nano-TiO2 reduced energy consumption in carbohydrate metabolism and TCATitanium dioxide nanoparticle (nano-TiO2), as an excellent UV absorbent and photo-catalyst, has beenWe proposed that nano-TiO2 in soil can promote crop yield through photosynthetic and metabolic disturbanceResults showed that rice biomass was increased >30% at every applied dosage (0.1–100 mg/L) of nano-TiO2.

Keywords： Nano-TiO2sub> Rice Photosynthesis Metabolomics Energy storage

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Title Author Date Type Operation

Enhanced 4-chlorophenol biodegradation by integrating FeO nanoparticles into an anaerobic reactor: Long-term

Journal Article

Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Journal Article

Size and shape effects of MnFeO nanoparticles as catalysts for reductive degradation of dye pollutants

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2sub>O3sub> Systemwith Al2sub>O3sub> and Cr2sub>O3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article

Sulfur-deficient CoNi2sub>S4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

Journal Article

CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

In-MOF-derived In2sub>S3sub>/Bi2sub>S3sub> heterojunction for enhanced photocatalytic

Journal Article

Fe3sub>O4sub> encapsulated mesoporous silica nanospheres with tunable size and large void

Tingting LIU, Lihong LIU, Jian LIU, Shaomin LIU, Shi Zhang QIAO

Journal Article

Effects of iron oxide nanoparticles on phenotype and metabolite changes in hemp clones ( L.)

Journal Article

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties

Journal Article

Feasibility study of plasma sprayed Al2sub>O3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Journal Article

Spray Preparation, Microstructure and Properties of Al2sub>O3sub>-Mxsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Journal Article

of promoted rice (Oryza sativa L.) growth by TiO2sub> nanoparticles

Yingdan Zhang, Na Liu, Wei Wang, Jianteng Sun, Lizhong Zhu

Journal Article

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